1.
no makeup; bare face
A face without any makeup; one's natural face.
すっぴん is a casual word primarily used in conversation about cosmetics and appearance. It is usually explained as 素 (bare, plain) + an emphatic ぴん; the details of the origin are uncertain.
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This is casual/colloquial language. In more formal contexts, use 素顔 (natural face) or ノーメイク.